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Valentine is an unincorporated community and census-designated place (CDP) in Mohave County, Arizona, United States. As of the 2020 census it had a population of 39. Valentine is located on Arizona State Route 66 32 miles (51 km) northeast of Kingman. The majority of Valentine is located in a geographically isolated exclave of the Hualapai Reservation and the rest of the community is located in unincorporated Mohave County.